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    • 专利摘要:
    A method of manufacturing a part (20) comprising a formation of successive metal layers (201… 20n), superimposed on each other, each layer being formed by the deposition of a filler metal (15, 25), the filler metal being subjected to an energy input so as to melt and to form, by solidifying, said layer, the method being characterized in that the filler metal (15, 25) is an alloy of 'aluminum having the following alloying elements (% by weight): Zr: 0.5% to 2.5%, preferably 0.8% to 2.5%, preferably 1% to 2.5%, plus preferably 1.3% to 2.5%. ; Fe: 0% to 3%, preferably 0.5% to 2.5%; optionally Si: ≤ 0.3%, preferably ≤ 0.2%, more preferably ≤ 0.1%; optionally Cu: ≤ 0.5%, preferably 0.05 to 0.5%; optionally Mg: ≤ 0.2%, preferably ≤ 0.1%, preferably <0.05%; other alloying elements <0.1% individually, and in total <0.5%; impurities: <0.05% individually, and in total <0.15%; remains aluminum. FIGURES
    公开号:FR3092120A1
    申请号:FR1908684
    申请日:2019-07-30
    公开日:2020-07-31
    发明作者:Bechir Chehab
    申请人:C Tec Constellium Technology Center SAS；
    IPC主号:
    专利说明:

    [0001] The technical field of the invention is a process for manufacturing an aluminum alloy part, implementing an additive manufacturing technique.
    [0002] PRIOR ART
    [0003] Since the 1980s, additive manufacturing techniques have developed. They consist of shaping a part by adding material, which is the opposite of machining techniques, which aim to remove material. Formerly confined to prototyping, additive manufacturing is now operational to manufacture industrial products in series, including metal parts.
    [0004] The term “additive manufacturing” is defined according to the French standard XP E67-001 as a “set of processes making it possible to manufacture, layer by layer, by adding material, a physical object from a digital object”. ASTM F2792 (January 2012) also defines additive manufacturing. Different additive manufacturing methods are also defined and described in the ISO/ASTM 17296-1 standard. The use of additive manufacturing to produce an aluminum part, with low porosity, has been described in document WO2015006447. The application of successive layers is generally carried out by applying a so-called filler material, then melting or sintering the filler material using an energy source such as a laser beam, electron beam, plasma torch or electric arc. Regardless of the additive manufacturing modality applied, the thickness of each added layer is of the order of a few tens or hundreds of microns.
    [0005] Other additive manufacturing methods can be used. Let us cite for example, and in a non-limiting manner, the melting or sintering of a filler material taking the form of a powder. It can be melting or laser sintering. Patent application US20170016096 describes a process for manufacturing a part by localized melting obtained by exposing a powder to an energy beam of the electron beam or laser beam type, the process also being designated by the acronyms Anglo-Saxon SLM, meaning "Selective Laser Melting" or "EBM", meaning "Electro Beam Melting".
    [0006] The mechanical properties of aluminum parts obtained by additive manufacturing depend on the alloy forming the filler metal, and more precisely on its composition as well as on the heat treatments applied following the implementation of additive manufacturing.
    [0007] The applicant has determined an alloy composition which, when used in an additive manufacturing process, makes it possible to obtain parts with remarkable mechanical performance, without it being necessary to implement heat treatments of the solution treatment and quenching type. . In addition, the parts used have interesting properties of thermal conductivity or electrical conductivity. This makes it possible to diversify the application possibilities of these parts.
    [0008] A first object of the invention is a process for manufacturing a part comprising the formation of successive metal layers, superimposed on each other, each layer being formed by the deposition of a filler metal, the filler metal being subjected to a supply of energy so as to enter into fusion and to constitute, while solidifying, said layer, the method being characterized in that the filler metal is an aluminum alloy comprising the following alloying elements (% in weight) :
    [0009] Zr: 0.5% to 2.5%, preferably 0.8% to 2.5%, preferably 1% to 2.5%, more preferably 1.3% to 2.5%. ; Fe: 0% to 3%, preferably 0.5% to 2.5%; optionally Si: ≤ 0.3%, preferably ≤ 0.2%, more preferably ≤ 0.1%; optionally Cu: ≤ 0.5%, preferably 0.05 to 0.5%; optionally Mg: ≤0.2%, preferably ≤0.1%, preferably <0.05%; other alloying elements <0.1% individually, and in total <0.5%; impurities: <0.05% individually, and in total <0.15%;
    [0010] remains aluminum.
    [0011] Other alloying elements include, for example, Cr, V, Ti, Mn, Mo, W, Nb, Ta, Sc, Ni, Zn, Hf, Nd, Ce, Co, La, Ag, Li, Y, Yb , Er, Sn, In, Sb, Sr, Ba, Bi, Ca, P, B and/or mischmetal.
    [0012] Preferably, the method may include the following characteristics, taken individually or according to technically feasible combinations:
    [0013] Zr: 0.8 to 2.5%, or preferably 1% to 2.5%, or more preferably 1.2% to 2.5%, or more preferably 1.3% to 2.5% or more preferably 1.5% to 2.5%; Fe: 0.5% to 2.5% or 0.5% to 2%; Si: <0.2% and preferably <0.1%; If ≥ 0.01%, or even ≥ 0.05%; Cu: 0.05% to 0.5%; Zr: 0.5% to 2.5% and Fe ≥ 1%; Zr: 0.5% to 2.5% and Fe < 1%; the mass fraction of each other alloying element is strictly less than 500 ppm, 300 μm, 200 ppm, or even 100 ppm. the alloy does not contain Cr, V, Mn, Ti, Mo, or according to a mass fraction of less than 500 ppm, 300 ppm, 200 ppm or even less than 100 ppm;
    [0014] Each layer can in particular describe a pattern defined from a digital model.
    [0015] The method may comprise, following the formation of the layers, an application of at least one heat treatment. The heat treatment may be or include tempering or annealing. It may also include solution treatment and quenching, even if it is preferred to avoid them. It may also include hot isostatic pressing.
    [0016] In order to favor the mechanical properties, the heat treatment can be carried out:
    [0017] at a temperature above 400° C., in which case the duration of the heat treatment is between 0.1 h and 10 h; or at a temperature comprised from 300° C. to 400° C., in which case the duration of the heat treatment is comprised from 0.5 h to 100 h.
    [0018] In order to favor the properties of thermal or electrical conduction, the heat treatment can be carried out at a temperature greater than or equal to 350° C. or 400° C., or a duration of 90 to 200 h, so as to obtain a thermal conductivity or optimum electricity. For example a temperature of 380 to 470°C and a duration of 90 to 110 h.
    [0019] According to an advantageous embodiment, the method does not include quenching following the formation of the layers or the heat treatment. Thus, preferably, the method does not include solution treatment steps followed by quenching.
    [0020] According to one embodiment, the filler metal takes the form of a powder, the exposure of which to a beam of light or charged particles results in localized melting followed by solidification, so as to form a solid layer . According to another embodiment, the filler metal comes from a filler wire, the exposure of which to an electric arc results in localized melting followed by solidification, so as to form a solid layer.
    [0021] A second object of the invention is a metal part, obtained after application of a method according to the first object of the invention.
    [0022] A third object of the invention is a filler material, in particular a filler wire or a powder, intended to be used as a filler material for an additive manufacturing process, characterized in that it is made of an aluminum alloy, comprising the following alloying elements (% by weight):
    [0023] Zr: 0.5% to 2.5%, preferably 0.8% to 2.5%, preferably 1% to 2.5%, more preferably 1.3% to 2.5%. ; Fe: 0% to 3%, preferably 0.5% to 2.5%; optionally Si: ≤ 0.3%, preferably ≤ 0.2%, more preferably ≤ 0.1%; optionally Cu: ≤ 0.5%, preferably 0.05 to 0.5%; optionally Mg: ≤0.2%, preferably ≤0.1%, preferably <0.05%; other alloying elements <0.1% individually, and in total <0.5%; impurities: <0.05% individually, and in total <0.15%;
    [0024] remains aluminum.
    [0025] The aluminum alloy forming the filler material may have the characteristics described in connection with the first object of the invention.
    [0026] The filler material may be in the form of a powder. The powder may be such that at least 80% of the particles making up the powder have an average size in the following range: 5 μm to 100 μm, preferably 5 to 25 μm, or 20 to 60 μm.
    [0027] When the filler material is in the form of a wire, the diameter of the wire may in particular be between 0.5 mm and 3 mm, and preferably between 0.5 mm and 2 mm, and even more preferably included from 1 mm to 2 mm.
    [0028] Other advantages and characteristics will emerge more clearly from the following description of particular embodiments of the invention, given by way of non-limiting examples, and represented in the figures listed below.
    [0029] FIGURES
    [0030] Figure 1 is a diagram illustrating an SLM-type additive manufacturing process.
    [0031] Figure 2 illustrates tensile and electrical conduction properties determined during the experimental tests of Example 1, from samples manufactured by implementing an additive manufacturing process according to the invention.
    [0032] Figure 3 is a diagram illustrating a WAAM-type additive manufacturing process.
    [0033] Figure 4 is a diagram of the test specimen used according to the examples.
    [0034] Figure 5 is a schematic of the second test pieces of Example 1.
    [0035] FIG. 6 illustrates tensile and electrical conduction properties determined during the experimental tests of example 2, from samples manufactured by implementing an additive manufacturing method according to the invention.
    [0036] DESCRIPTION OF PARTICULAR EMBODIMENTS
    [0037] In the description, unless otherwise stated:
    [0038] the designation of aluminum alloys is in accordance with the nomenclature of The Aluminum Association; the contents of chemical elements are designated in % and represent mass fractions. The notation x% - y% means greater than or equal to x% and less than or equal to y%.
    [0039] By impurity, we mean chemical elements present in the alloy in an unintentional way.
    [0040] Figure 1 schematizes the operation of an additive manufacturing process of the selective laser melting type (Selective Laser Melting or SLM). The filler metal 15 is in the form of a powder placed on a support 10. An energy source, in this case a laser source 11, emits a laser beam 12. The laser source is coupled to the material of contribution by an optical system 13, the movement of which is determined according to a digital model M . The laser beam 12 propagates along a propagation axis Z, and follows a movement along an XY plane, describing a pattern depending on the digital model. The plane is for example perpendicular to the axis of propagation Z. The interaction of the laser beam 12 with the powder 15 generates a selective melting of the latter, followed by a solidification, resulting in the formation of a layer 20 1 ... 20 n . When a layer has been formed, it is covered with powder of the filler metal and another layer is formed, superimposed on the previously produced layer. The thickness of the powder forming a layer can for example be between 10 and 200 μm.
    [0041] The powder may have at least one of the following characteristics:
    [0042] Average particle size 5 to 100 µm, preferably 5 to 25 µm, or 20 to 60 µm. The values given mean that at least 80% of the particles have an average size within the specified range. Spherical shape. The sphericity of a powder can for example be determined using a morphogranulometer. Good flowability. The flowability of a powder can for example be determined according to the ASTM B213 standard or the ISO 4490:2018 standard. According to ISO 4490:2018, the flow time is preferably less than 50. Low porosity, preferably 0 to 5%, more preferably 0 to 2%, even more preferably 0 to 1% by volume. The porosity can in particular be determined by image analysis from optical micrographs or by helium pycnometry (see the ASTM B923 standard). Absence or small quantity (less than 10%, preferably less than 5% by volume) of small particles (1 to 20% of the average size of the powder), called satellites, which stick to the larger particles.
    [0043] The implementation of such a method allows parts to be manufactured at a high yield, which can reach 40 cm 3 /h.
    [0044] Furthermore, the applicant has observed that the application of heat treatments of the quenching type could induce a distortion of the part, due to the sudden variation in temperature. The distortion of the part is generally all the more significant as its dimensions are important. However, the advantage of an additive manufacturing process is precisely to obtain a part whose shape, after manufacturing, is definitive, or quasi-definitive. The occurrence of significant deformation resulting from heat treatment should therefore be avoided. By quasi-final, it is understood that a finishing machining can be carried out on the part after its manufacture: the part manufactured by additive manufacturing extends according to its final shape, except for the finishing machining.
    [0045] Having observed the foregoing, the applicant sought an alloy composition, forming the filler material, making it possible to obtain acceptable mechanical properties, without requiring the application of heat treatments, subsequent to the formation of the layers, risking induce distortion. This involves in particular avoiding heat treatments involving a sudden change in temperature. Thus, the invention makes it possible to obtain, by additive manufacturing, a part whose mechanical properties are satisfactory, in particular in terms of elastic limit. Depending on the type of additive manufacturing process chosen, the filler material can be in the form of a wire or a powder.
    [0046] The applicant has found that by limiting the number of elements present in the alloy having a content above 1% by mass, a good compromise is obtained between the interesting mechanical and thermal properties. It is usually accepted that the addition of elements in the alloy makes it possible to improve certain mechanical properties of the part produced by additive manufacturing. By mechanical properties is meant, for example, the elastic limit or the elongation at break. However, adding too much, or too much diversity, of chemical alloying elements can adversely affect the heat conduction properties of the part resulting from additive manufacturing. Thus, the use of binary or ternary alloys, in an additive manufacturing process, constitutes a promising path in the field of additive manufacturing.
    [0047] The applicant considered that it was useful to arrive at a compromise between the number and the quantity of the elements added to the alloy, so as to obtain acceptable mechanical and thermal (or electrical) properties.
    [0048] The applicant considers that such a compromise is obtained by limiting to one or two the number of chemical elements forming the aluminum alloy having a mass fraction greater than or equal to 1%. Thus, a particularly interesting alloy can be obtained by adding, according to a mass fraction greater than 1%:
    [0049] Zr only, in which case the alloy is essentially made up of two elements (Al and Zr). For example Zr: 0.5% to 2.5% and Fe ≥ 1%; or Zr and Fe in which case the alloy is essentially made up of three elements (Al, Zr and Fe). The presence of Fe in the alloy makes it possible to improve the mechanical properties, whether these are mechanical tensile properties or hardness. For example Zr: 0.5% to 2.5% and Fe < 1%.
    [0050] The presence of Zr in the alloy confers good processability of the alloy, the term processability corresponding to the Anglo-Saxon designation "processability", qualifying the ability to be shaped by an additive manufacturing process. This is reflected, at the level of a part manufactured by additive manufacturing, by a virtual absence of defects, of the cracking type, and low porosity. The applicant has observed that a mass fraction of Zr greater than 0.5% confers good processability. An optimum mass fraction of Zr is between 1.2% or 1.3% and 2.5%. When Zr is less than 0.5%, the mechanical properties are generally not sufficient.
    [0051] The Applicant has observed in the SLM process and in the presence of Zr, in particular for a Zr content > 0.5%), during the solidification of each layer, equiaxed grains forming at the bottom of the lasing bead from precipitates Primary Al 3 Zr that form in the liquid. The primary Al 3 Zr precipitates serve as seeds, from which equiaxed grains of aluminum are formed. The rest of the lasage bead solidifies in the form of columnar grains which grow from the edge towards the center of the bead in a radial manner. The higher the Zr content, the greater the fraction of equiaxed grains and the lower the fraction of columnar grains. The presence of a sufficient fraction of equiaxed grains is beneficial to avoid cracking at the end of solidification.
    [0052] However, when the Zr content is <0.5%, the concentration of primary Al 3 Zr precipitates is too low, which leads to the formation of coarse columnar grains which can cross several layers, according to an epitaxial growth, progressing from one layer to another layer. The part obtained is thus more sensitive to solidification cracking.
    [0053] This effect of the Zr content on the sensitivity to cracking is specific to additive manufacturing processes with melting of each layer such as the SLM process. In the case of a non-additive process such as the conventional so-called rapid solidification processes with compacting and spinning of parts from rapidly solidified fine ribbons or powder, parts made of alloys with Zr contents < 0.5% can be manufactured without cracking. Indeed, these processes do not require melting during the forming step and are therefore not subject to solidification cracks.
    [0054] The applicant has also observed that the presence of copper makes it possible to improve the mechanical properties and the electrical conductivity/elastic limit compromise after heat treatment.
    [0055] Preferably, the mass fraction of Zr ranges from 0.5% to 2.5%, or even from 0.8% to 2.5%, or even from 1% to 2.5%, or even from 1.2% to 2.5%, or even 1.3% to 2.5%, or even 1.5% to 2.5%.
    [0056] When the alloy contains Fe, the mass fraction of Fe is less than or equal to 3%. It is preferably between 0.5% and 3%. A combination of Zr and Fe is particularly advantageous, as previously mentioned, and confirmed by experimental tests.
    [0057] The alloy may also include other alloying elements, such as Cr, V, Ti, Mn, Mo, W, Nb, Ta, Sc, Ni, Zn, Hf, Nd, Ce, Co, La, Ag, Li, Y, Yb, Er, Sn, In, Sb, Sr, Ba, Bi, Ca, P, B and/or mischmetal, according to a mass fraction individually strictly less than 0.1%, preferably less than 500 ppm, and preferably less than 300 ppm, or 200 ppm, or 100 ppm. However, some of these alloying elements, especially Cr, V, Ti and Mo degrade conductivity. Cu is considered less detrimental with respect to thermal conductivity.
    [0058] The addition of Mg in the absence of solution-quenching-tempering treatment would lower the electrical or thermal conductivity without significant impact on the mechanical properties. Added to this is its tendency to evaporate during the atomization and SLM process, especially for high liquidus alloys such as those tested according to the present invention. Thus, according to a variant, the alloy used according to the present invention does not comprise Mg or else according to a quantity of impurity, i.e. <0.05%.
    [0059] When the alloy comprises other alloying elements, such as Y, Yb, Er, Sn, In, Sb, they are preferably present in a mass fraction strictly less than 500 ppm, or even strictly less than 300 ppm, or even strictly less than 200 ppm or 100 ppm.
    [0060] It should be noted that, preferably, the alloys according to the present invention are not AA6xxx type alloys, due to the absence of simultaneous addition of Si and Mg in quantities greater than 0.2%.
    [0061] Experimental examples
    [0062] Example 1
    [0063] Initial tests were carried out using an alloy 1, whose mass composition measured by ICP comprised Zr: 1.52%; Fe 213ppm; If 183ppm; impurities: <0.05% each with cumulative impurities <0.15%.
    [0064] Test parts were made by SLM, using an EOS290 SLM type machine (EOS supplier). The laser power was 370 W. The scanning speed was equal to 1400 mm/s. The gap between two adjacent scan lines, usually referred to as the "vector gap", was 0.11 mm. The layer thickness was 60 µm.
    [0065] The powder used had a particle size essentially ranging from 3 μm to 100 μm, with a median of 40 μm, a 10% fractile of 16 μm and a 90% fractile of 79 μm.
    [0066] The first test pieces were made, in the form of cylinders vertical to the construction plate (Z direction) with a diameter of 11 mm and a height of 46 mm. Second test pieces were made, taking the form of parallelepipeds of dimensions 12 (X direction) x 45 (Y direction) x 46 (Z direction) mm (see Figure 5). All parts have undergone a post-manufacturing SLM stress relief treatment of 4 hours at 300°C.
    [0067] . Some first parts underwent a post-manufacturing heat treatment at 350°C, 400°C or 450°C, the duration of the treatment being between 1 hour and 104 hours. All the first parts (with and without post-manufacturing heat treatment) were machined to obtain cylindrical tensile specimens with the following characteristics in mm (see Table 1 and Figure 4):
    [0068] In Figure 4 and Table 1, Ø represents the diameter of the central part of the specimen, M the width of the two ends of the specimen, LT the total length of the specimen, R the radius of curvature between the center and the ends of the specimen, Lc the length of the central part of the specimen and F the length of the two ends of the specimen.
    [0069] Type Ø M LT R lc F digital 4 4 8 45 3 22 8.7
    [0070] These cylindrical specimens were tensile tested at room temperature according to standard NF EN ISO 6892-1 (2009-10).
    [0071] Certain second test parts have undergone post-manufacturing heat treatment, as described in connection with the first parts. The second test pieces were subjected to electrical conductivity tests, based on the fact that electrical conductivity evolves similarly to thermal conductivity. A linear dependence relationship of thermal conductivity and electrical conductivity, according to Wiedemann Franz's law, was validated in the Hatch publication "Aluminium properties and physical metallurgy" ASM Metals Park, OH, 1988. The second test pieces were undergone a surface polishing on each face of 45 mm x 46 mm for the conductivity measurements using an abrasive paper of roughness 180. The electrical conductivity measurements were carried out on the polished faces using a Foerster Sigmatest 2.069 at 60 kHz type measurement.
    [0072] Table 2 below represents, for each first test piece, the heat treatment temperature (°C), the heat treatment time, the yield strength at 0.2% Rp0.2 (MPa), the resistance to traction (Rm), the elongation at break A (%), as well as the electrical conductivity (MS.m -1 ). The tensile properties (yield strength, tensile strength and elongation at break) were determined from the first test pieces, according to the manufacturing direction Z, while the electrical properties (electrical conductivity) were determined on the second test pieces. In Table 2 below, the duration of 0 h corresponds to an absence of heat treatment.
    [0073] Duration (h) Temple deletion (°C) Rp0 .2 ( MPa ) rm ( MPa ) AT (%) σ (MS/m) 0 - 109 148 22 21.12 14 350 240 257 7.7 28.46 56 350 231 262 8.4 29.68 1 400 234 262 9.8 28.56 4 400 235 266 8.6 29.61 10 400 227 259 7.7 30.52 100 400 198 238 9.2 32.23 104 450 145 181 8.7 33.43
    [0074] Without application of a heat treatment, the mechanical properties are considered satisfactory. However, the application of an appropriate heat treatment makes it possible to improve the elastic limit, the tensile strength as well as the electrical conductivity. The beneficial effect of the heat treatment is attributed to the formation of nanometric Al 3 Zr precipitates, which leads to a simultaneous increase in the elastic limit and in the conductivity. In the absence of heat treatment, a fraction of Zr is kept trapped in solid solution.
    [0075] A remarkable aspect is that the heat treatment makes it possible to very significantly increase the electrical conductivity, the latter approaching that of pure aluminum (close to 34 MS/m), while also increasing the mechanical properties compared to those of pure aluminum.
    [0076] The parameters allowing good mechanical properties to be obtained are as follows:
    [0077] at 400° C., the duration being between 1 h and 10 h; at 350° C., the duration being comprised from 10 h to 100 h, knowing that a duration comprised from 10 h to 20 h seems sufficient.
    [0078] Also, when a heat treatment is applied, it is preferable that its temperature be lower than 500°C. When it is preferred to obtain optimum mechanical properties, the temperature of the heat treatment is preferably less than 450° C., and for example comprised from 300° C. to 420° C.
    [0079] When electrical or thermal conduction is preferred, the temperature of the heat treatment is preferably greater than or equal to 350° C. or even 400° C., with a duration which may exceed 100 h, for example from 90 to 200 h.
    [0080] It is observed that when the heat treatment is carried out at 400° C., the evolution of the mechanical tensile properties (yield point, tensile strength), as a function of the duration of the treatment, is first of all increasing, then decreasing. An optimal duration of heat treatment makes it possible to optimize the mechanical tensile properties. It is between 0.1 h and 10 h at 400°C.
    [0081] The heat treatment is preferably tempering or annealing.
    [0082] Figure 2 illustrates the tensile properties (axis of ordinates, representing the elastic limit Rp0.2 expressed in MPa) according to the properties of thermal conductivity (axis of abscissas, representing the thermal conductivity expressed in MS/m)). It is recalled that the thermal conduction properties are assumed to be representative of the electrical conduction properties. In Figure 2, the percentages indicate the elongation at break. The beneficial effect of the heat treatment has been represented by an arrow, both from the point of view of the electrical conductivity and of the elastic limit. In the legend of Figure 2, the term "raw" means an absence of heat treatment.
    [0083] The relative density of the samples was greater than 99.5%, which reflects a porosity <0.5%, the latter having been estimated by image analysis on a section of polished samples.
    [0084] A second test was carried out using:
    [0085] an alloy 1 as described above; an alloy2, whose mass composition measured by ICP included Al; Zr 1.78%; Fe 1.04%; If 1812 ppm; Cu 503ppm; impurities < 0.05% each with cumulative impurities < 0.15%.
    [0086] Test pieces similar to those described in connection with the first test were formed.
    [0087] The powder used had a particle size essentially ranging from 3 μm to 100 μm, with a median of 41 μm, a 10% fractile of 15 μm and a 90% fractile of 82 μm.
    [0088] The Vickers Hv0.2 hardness was characterized, according to the ASTM E384 standard, as well as the electrical conductivity, on parallelepipedal parts. The hardness and conductivity measurements were carried out in the absence of heat treatment as well as after various heat treatments.
    [0089] Table 3 presents the results of the characterizations. N/A means the feature was not measured.
    [0090] Alloy Thermal treatment H v 0.2 Electrical conductivity (Ms/m) Alloy 2 any 79 18.11 Alloy 2 400°C – 1 hour 92 24 Alloy 2 400°C -4 hours 99 26 Alloy 1 any 51.2 21.12 Alloy 1 400°C – 4h 93 29.61
    [0091] The tests confirm that:
    [0092] the presence of Fe significantly improves the mechanical properties; the application of a heat treatment improves the mechanical and electrical conduction properties.
    [0093] Example 2
    [0094] A second test similar to that of example 1 was carried out using alloy 2 as described above in connection with example 1.
    [0095] The powder used had a particle size essentially ranging from 3 μm to 100 μm, with a median of 41 μm, a 10% fractile of 15 μm and a 90% fractile of 82 μm.
    [0096] Test parts were produced by SLM, using an EOS M290 SLM type machine (EOS supplier). The laser power was 370 W. The scanning speed was equal to 1250 mm/s. The gap between two adjacent scan lines, usually referred to as the "vector gap", was 0.111 mm. The layer thickness was 60 µm.
    [0097] As for Example 1, the addition of a heat treatment for up to 100 h at 400° C. or 450° C. made it possible to simultaneously increase the mechanical resistance and the electrical conductivity compared to the raw state of relaxation, as illustrated in Table 4 below and Figure 6.
    [0098] Duration (h) Temperature (°C) Rp0.2 (MPa) rm (MPa) AT (%) σ (MS/m) 0 - 214 240 16.8 18.11 14 350 288 301 10.5 24.23 56 350 284 300 6.9 26.62 1 400 298 307 7.8 24.00 4 400 272 293 9.1 26.19 10 400 275 292 5.8 27.55 100 400 215 238 16.9 29.98 104 450 221 244 12.5 30.00
    [0099] Alloy 2 made it possible to show the positive impact of the addition of Fe on the increase in the elastic limit Rp02 and the breaking strength Rm (without significant degradation of the electrical conductivity) compared to the alloy 1 of example 1. This alloy 2 made it possible to reach, after heat treatment, Rp02 and Rm values not attainable by alloy 1 of example 1, with Rp02 values greater than 260 MPa while maintaining an electrical conductivity greater than 24 MS/m or even 26 MS/m.
    [0100] Without being bound by theory, it would seem that in parts made by conventional processes such as machining from blocks obtained by wrought iron, Fe is present in the form of coarse intermetallics with a size of up to a few tens of µm. On the contrary, in the parts manufactured by selective laser melting from alloy 2 of example 2, the Fe is present in the form of nanometric precipitates which do not have a negative impact on the corrosion resistance nor on the suitability of the alloy for anodization. The presence of Fe-based nanometric precipitates seems, on the contrary, to have a positive impact on corrosion resistance by leading to lateralized and non-localized corrosion of the parts tested.
    [0101] According to one embodiment, the method may include hot isostatic pressing (CIC). The CIC treatment can in particular make it possible to improve the elongation properties and the fatigue properties. Hot isostatic pressing can be performed before, after or instead of heat treatment. Advantageously, the hot isostatic pressing is carried out at a temperature of 250° C. to 500° C. and preferably of 300° C. to 450° C., at a pressure of 500 to 3000 bars and for a duration of 0.5 to 50 time.
    [0102] The possible heat treatment and/or hot isostatic pressing makes it possible in particular to increase the hardness or the elastic limit and the electrical conductivity of the product obtained.
    [0103] According to another embodiment, suitable for structural hardening alloys, solution treatment followed by quenching and tempering of the formed part and/or hot isostatic pressing can be carried out. Hot isostatic pressing can in this case advantageously replace solution treatment.
    [0104] However, the process according to the invention is advantageous, because it preferably does not require solution treatment followed by quenching. Dissolution can have a detrimental effect on the mechanical resistance in certain cases by participating in a coarsening of the dispersoids or of the fine intermetallic phases.
    [0105] According to one embodiment, the method according to the present invention also optionally comprises a machining treatment, and/or a chemical, electrochemical or mechanical surface treatment, and/or a tribofinishing. These treatments can be carried out in particular to reduce the roughness and/or improve the resistance to corrosion and/or improve the resistance to the initiation of fatigue cracks.
    [0106] Optionally, it is possible to carry out a mechanical deformation of the part, for example after additive manufacturing and/or before heat treatment.
    [0107] Although described in connection with an additive manufacturing method of the SLM type, the method can be applied to other additive manufacturing methods of the WAAM type, mentioned in connection with the prior art. Figure 3 shows such an alternative. An energy source 31, in this case a torch, forms an electric arc 32. In this device, the torch 31 is held by a welding robot 33. The part 20 to be manufactured is placed on a support 10. In this example, the manufactured part is a wall extending along a transverse axis Z perpendicular to an XY plane defined by the support 10. Under the effect of the electric arc 12, a filler wire 35 merges to form a weld bead. The welding robot is controlled by a digital model M . It is moved so as to form different layers 20 1 ... 20 n , stacked on top of each other, forming the wall 20, each layer corresponding to a weld bead. Each layer 20 1 …20 n extends in the XY plane, according to a pattern defined by the numerical model M .
    [0108] The diameter of the filler wire is preferably less than 3 mm. It can be comprised from 0.5 mm to 3 mm and is preferably comprised from 0.5 mm to 2 mm, or even from 1 mm to 2 mm. It is for example 1.2 mm.
    [0109] Other methods are also possible, for example, and in a non-limiting manner:
    [0110] - selective laser sintering (Selective Laser Sintering or SLS);
    [0111] - direct metal sintering by laser (Direct Metal Laser Sintering or DMLS); - selective sintering by heating (Selective Heat Sintering or SHS); - electron beam melting (Electron Beam Melting or EBM); - deposition by laser melting (Laser Melting Deposition); - Direct Energy Deposition (DED); - direct metal deposition (Direct Metal Deposition or DMD); - direct laser deposition (Direct Laser Deposition or DLD); - Laser Deposition Technology; - engineering of net shapes by laser (Laser Engineering Net Shaping); - laser cladding technology; - laser freeform manufacturing technology (LFMT); - deposition by laser fusion (Laser Metal Deposition or LMD); - cold spraying (Cold Spray Consolidation or CSC); - additive manufacturing by friction (Additive Friction Stir or AFS); - plasma spark sintering or flash sintering (Field Assisted Sintering Technology, FAST or spark plasma sintering); Where - rotary friction welding (Inertia Rotary Friction Welding or IRFW).
    权利要求:
    Claims (13)
    [0001]
    Method of manufacturing a part (20) comprising forming successive metal layers (201…20not), superimposed on each other, each layer being formed by the deposition of a filler metal (15, 25), the filler metal being subjected to a supply of energy so as to enter into fusion and to constitute , by solidifying, said layer, the method being characterized in that the filler metal (15, 25) is an aluminum alloy comprising the following alloying elements (% by weight):Zr: 0.5% to 2.5%, preferably 0.8% to 2.5%, preferably 1% to 2.5%, more preferably 1.3% to 2.5%. ; Fe: 0% to 3%, preferably 0.5% to 2.5%; optionally Si: ≤ 0.3%, preferably ≤ 0.2%, more preferably ≤ 0.1%; optionally Cu: ≤ 0.5%, preferably 0.05 to 0.5%; optionally Mg: ≤0.2%, preferably ≤0.1%, preferably <0.05%; other alloying elements <0.1% individually, and in total <0.5%; impurities: <0.05% individually, and in total <0.15%; remains aluminum.
    [0002]
    Process according to Claim 1, in which the other elements are chosen from: Cr, V, Ti, Mn, Mo, W, Nb, Ta, Sc, Ni, Zn, Hf, Nd, Ce, Co, La, Ag, Li , Y, Yb, Er, Sn, In, Sb, Sr, Ba, Bi, Ca, P, B and/or mischmetal.
    [0003]
    A method according to any preceding claim, wherein the mass fraction of each other alloying element is less than 300 ppm, or even less than 200 ppm, or even less than 100 ppm.
    [0004]
    A method according to any preceding claim, wherein:Zr: 0.5% to 2.5%; Fe ≥ 1%.
    [0005]
    Process according to any one of claims 1 to 3, in which:Zr: 0.5% to 2.5%; Fe: < 1%.
    [0006]
    Method according to any one of the preceding claims, comprising, following the formation of the layers (20 1 …20 n ), an application of a heat treatment.
    [0007]
    A method according to claim 6, wherein the heat treatment is tempering or annealing.
    [0008]
    Process according to any one of claims 6 or 7, in which the heat treatment is carried out:at a temperature above 400° C., in which case the duration of the heat treatment is between 0.1 h and 10 h; or at a temperature comprised from 300°C to 400°C, in which case the duration of the heat treatment is comprised from 0.5 h to 100 h.
    [0009]
    Process according to any one of Claims 6 or 7, in which the heat treatment is carried out at a temperature greater than or equal to 350°C or even 400°C, or a duration of 90 to 200 hours, so as to obtain a thermal conductivity or optimum electricity.
    [0010]
    A method according to any preceding claim, including no quenching following layer formation or heat treatment.
    [0011]
    A method according to any preceding claim, wherein the filler metal takes the form of a powder (15), the exposure of which to a beam of light (12) or charged particles results in localized melting followed solidification, so as to form a solid layer (20 1 …20 n ).
    [0012]
    A method as claimed in any one of claims 1 to 10, wherein the filler metal being derived from a filler wire (25), the exposure of which to a heat source (22) results in localized melting followed solidification, so as to form a solid layer (20 1 …20 n ).
    [0013]
    Powder, intended to be used as filler material for an additive manufacturing process, characterized in that it consists of an aluminum alloy, comprising the following alloying elements (% by weight):Zr: 0.5% to 2.5%, preferably 0.8% to 2.5%, preferably 1% to 2.5%, more preferably 1.3% to 2.5%. ; Fe: 0% to 3%, preferably 0.5% to 2.5%; optionally Si: ≤ 0.3%, preferably ≤ 0.2%, more preferably ≤ 0.1%; optionally Cu: ≤ 0.5%, preferably 0.05 to 0.5%; optionally Mg: ≤0.2%, preferably ≤0.1%, preferably <0.05%; other alloying elements <0.1% individually, and in total <0.5%; impurities: <0.05% individually, and in total <0.15%; remains aluminum.
    类似技术:
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    同族专利:
    公开号 | 公开日
    KR20210118131A|2021-09-29|
    CA3125851A1|2020-05-14|
    FR3092119A1|2020-07-31|
    CN113348262A|2021-09-03|
    CA3125747A1|2020-07-30|
    FR3092120B1|2021-08-13|
    DE20707710T1|2022-03-17|
    CN113330132A|2021-08-31|
    FR3092119B1|2020-12-25|
    KR20210118132A|2021-09-29|
    EP3914748A1|2021-12-01|
    EP3914746A2|2021-12-01|
    WO2020152427A1|2020-07-30|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    FR2669844A1|1990-11-20|1992-06-05|Honda Motor Co Ltd|Aluminium alloy powder, green compacted product and sintered compacted product for powder metallurgy|
    WO2015006447A1|2013-07-10|2015-01-15|Alcoa Inc.|Methods for producing forged products and other worked products|
    US20170016096A1|2015-07-16|2017-01-19|Hamilton Sundstrand Corporation|Method of manufacturing aluminum alloy articles|
    EP3481971A4|2016-07-05|2019-12-25|Nanoal LLC|Ribbons and powders from high strength corrosion resistant aluminum alloys|
    JP2020515714A|2017-04-05|2020-05-28|アーエムアーゲー キャスティング ゲーエムベーハー|Starting materials, their use, and additional manufacturing processes using the starting materials|CN111872386B|2020-06-30|2021-12-31|同济大学|3D printing process method of high-strength aluminum-magnesium alloy|
    CN113512671A|2021-06-15|2021-10-19|中车工业研究院有限公司|High-toughness AlCrSc alloy powder for 3D printing and preparation method and application thereof|
    CN113430432B|2021-06-29|2022-03-01|哈尔滨工业大学|Preparation method of high-Zn light high-strength aluminum alloy|
    CN113444922A|2021-06-30|2021-09-28|赣州虔博新材料科技有限公司|Rare earth aluminum alloy conductor material and preparation method thereof|
    法律状态:
    2020-07-27| PLFP| Fee payment|Year of fee payment: 2 |
    2021-01-01| PLSC| Publication of the preliminary search report|Effective date: 20210101 |
    2021-07-26| PLFP| Fee payment|Year of fee payment: 3 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1900598|2019-01-24|
    FR1900598A|FR3092119B1|2019-01-24|2019-01-24|Process for manufacturing an aluminum alloy part, the alloy comprising at least zirconium and magnesium|KR1020217026604A| KR20210118131A|2019-01-24|2020-01-24|How to make aluminum alloy parts|
    CN202080010843.3A| CN113348262A|2019-01-24|2020-01-24|Method for manufacturing aluminum alloy parts|
    PCT/FR2020/050108| WO2020095009A2|2019-01-24|2020-01-24|Method for manufacturing an aluminum alloy part|
    CA3125851A| CA3125851A1|2019-01-24|2020-01-24|Method for manufacturing an aluminum alloy part|
    EP20706787.7A| EP3914746A2|2019-01-24|2020-01-24|Method for manufacturing an aluminum alloy part|
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